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Patent Approved: SILICA TO HIGH PURITY SILICON PRODUCTION PR

[developbc]

Patent Approved: SILICA TO HIGH PURITY SILICON PRODUCTION PROCESS

A new patent number has been provided and the patent itself is to be issued on March 8, 2022. The Patent Number is 11267714. Thanks to Pandora from SH for this. https://stockhouse.com/companies/bullboard?symbol=v.hpq&postid=34435701 This was a "patent application" by Pyrogensis on Feb. 5, 2018 (Application #15750331) It was then 'assigned' by Pyrogenesis to HPQ-Silicon Resources on August 1, 2018. The "Publication Number" and date are: 20180237306 Aug 23, 2018


Thanks Pandora for posting. This was a "patent application" by Pyrogensis on Feb. 5, 2018 (Application #15750331)

It was then 'assigned' by Pyrogenesis to HPQ-Silicon Resources on August 1, 2018.

The "Publication Number" and date are:

20180237306
Aug 23, 2018

 Here is more details: 

SILICA TO HIGH PURITY SILICON PRODUCTION PROCESS

PATENT NUMBER

20180237306

DOCUMENT ID

US 20180237306 A1

DATE PUBLISHED

2018-08-23

INVENTOR INFORMATION

NAME

CITY

STATE

ZIP CODE

COUNTRY

SHAHVERDI; Ali

Verdun

N/A

N/A

CA

CARABIN; Pierre

Montreal

N/A

N/A

CA

APPLICATION NO

15/750331

DATE FILED

2016-08-08

DOMESTIC PRIORITY (CONTINUITY DATA)

us-provisional-application US 62202452 20150807

US CLASS CURRENT:

1/1

CPC CURRENT

TYPE

CPC

DATE

CPCI

C 01 B 33/023

2013-01-01

CPCI

C 01 B 33/033

2013-01-01

CPCI

C 01 B 33/025

2013-01-01

CPCI

F 27 B 3/08

2013-01-01

Abstract

 

 

An apparatus and a process for the production of high purity silicon from silica containing material such as quartz or quartzite, using a vacuum electric arc furnace, are disclosed.

Background/Summary

 

 

CROSS REFERENCE TO RELATED APPLICATIONS [0001] This Application claims priority on U.S. Provisional Application No. 62/202,452, now pending, filed on Aug. 7, 2015, which is herein incorporated by reference.

 

 

FIELD

[0002] The present subject-matter relates to the production of silicon and, more particularly, to the production of silicon from silica.

BACKGROUND

[0003] One of the main processes for the production of silicon metal is based on the carbothermic reduction of silica at high temperature. This can be achieved by reducing silica in the presence of carbon in an electric arc furnace. The conventional method relies on the direct reduction of silica to silicon at ambient pressure where high temperature arc heats up the reactants to form silicon. The silicon product produced with this method is called Metallurgical Grade Silicon (MG-Si) with purities which are believed to be not greater than 98-99% at best. MG-Si is used directly in the aluminum and steel industry as an additive or is the precursor for production of higher purity grade silicon materials, such as Solar Grade silicon (SoG-Si) and Electronic Grade Silicon (EG-Si). Therefore, higher grade silicon is the product of the lower grade silicon (MG-Si) refined to the higher purity. Refining processes are the post-purification processes via two main routes: chemical route and metallurgical route.

[0004] Advances in solar energy and electronic applications have led silicon to become a strategic material in the twenty first century. Therefore, supply of high purity silicon at a reasonable cost has become a need.

[0005] The existing conventional carbothermic silicon production process has drawbacks and limitations which include, but are not limited to, high impurity content in the silicon which hinders its direct use in many applications such as solar energy, and high dependency to the raw material purity.

[0006] The following techniques are also known.

[0007] In U.S. Pat. No. 916,793, issued on Mar. 30, 1909 to Seward et al. and entitled “Production of Silicon”, reference [1], an arc furnace is utilized for direct carbothermic reduction of silica to silicon. A twin electrode direct current configuration is used to create the arcs between two cathodes and a bottom anode. Pure coke and substantially pure silica are used for the silicon production. No method has been therein proposed for the removal of either the CO (g) as the main by-product, or the condensed matter which forms during the process. This disclosure covers only a narrow range of the raw materials, those of extreme high purity (“pure”).

[0008] U.S. Pat. No. 3,215,522, issued on Nov. 2, 1965 to Kuhlmann and entitled “Silicon Metal Production”, reference [2], relates to a process for the production of silicon metal and silicon metal-bearing alloys in an electric arc furnace. Similarly to aforementioned U.S. Pat. No. 916,793, carbothermic reduction of silica is therein utilized for the silicon production in an electric arc furnace. The feed material consisting of either or both reactants (i.e. Silica and carbon sources) is fed through a hollow electrode to the furnace. Compared to U.S. Pat. No. 916,793, this disclosure is considered an improvement in which finer feed and less electrode consumption can be achieved. Hollow electrodes are utilized to carry fine-sized reactants into the furnace. Although the fine-sized particles have great tendency to clog in the line, this issue is not addressed in U.S. Pat. No. 3,215,522. Moreover, reactants could clog at the tip of the electrodes where the temperature is high enough to semi melt silica, which increases the chance of clogging. This issue is also not addressed in U.S. Pat. No. 3,215,522. U.S. Pat. No. 5,009,703, issued on Apr. 23, 1991 to Arvidson et al. and entitled “Silicon Smelting Process in Direct Current Furnace”, reference [3], targets enhancing the energy consumption of the prior techniques by applying a direct current (DC) in lieu of an alternating current (AC) system and performing the reduction process in a closed configuration of furnace in contrast to the open-top furnace. This disclosure provides a more energy efficient process for producing silicon metal using a DC power source in a closed-top furnace.

[0009] U.S. Pat. No. 5,104,096, issued on Apr. 14, 1992 to Goins, Jr. et al. and entitled “Smelting Apparatus for Making Elemental Silicon and Alloys Thereof”, reference [4], relates to the electrometallurgical methods and apparatus for the silicon metal production in a substantially pure form. Silicon dioxide is reduced with carbonaceous reductant in an electric arc furnace, wherein part of the silicon dioxide is reduced to silicon metal and part is converted to gaseous oxide. At least a portion of gaseous oxide is collected. By establishing and maintaining countercurrent contact between the collected oxide and a bed of carbonaceous reductant, additional elemental silicon is produced. Gas collection is done through one or more hollow electrodes or one or more drawoff tubes. This injection uses hollow electrodes or drawoff tubes to collect a portion of gaseous oxide, to be SiO (g). Using hollow tubes or electrodes to capture condensable gases is challenging and the chance of clogging is always present. However, in the present disclosure, this issue is not addressed. Although it is indicated that silicon produced by this method will be pure, the issue of impurities accumulation in the silicon phase is not therein addressed.

[0010] Therefore, it would be desirable to provide an apparatus and/or a process for producing high purity silicon from silica.

SUMMARY

[0011] It would thus be desirable to provide a novel apparatus and/or process for producing silicon from silica.

[0012] The embodiments described herein provide in one aspect a system for reducing silica to silicon, which uses a combination of a plasma arc and vacuum, to produce high purity silicon from silica containing materials, such as quartz or quartzite.

[0013] Specifically, a vacuum electric arc furnace is provided, such that the plasma arc produces a silicon melt from the silica containing materials.

[0014] More specifically, to enhance a volatilization rate of impurities contained in the silica containing materials, volatilizing agents, such as a chlorine containing material, are provided and are adapted to be injected through at least one hollow electrode into a melt produced in the furnace.

[0015] Also, the embodiments described herein provide in another aspect a vacuum electric arc furnace, comprising at least one set of hollow electrodes to generate an electric arc.

[0016] Specifically, there is provided at least one moving electrode, which is adapted to be displaced by a motion system to control the voltage(s) and which is electrically insulated from a body of furnace.

[0017] Furthermore, the embodiments described herein provide in another aspect a process where the reduction process of silica containing materials to high purity silicon takes place in a vacuum arc furnace, the hot gas evolving from the furnace being oxidized in a refractory-lined cyclone used to condense and collect impurities, and to oxidize combustible species, such as carbon monoxide.

[0018] Specifically, the gas is further cleaned of condensable particulates in a gas cooler-expander and in a high efficiency particulate air (HEPA) filtration system to capture very fine particulates.

[0019] Furthermore, the embodiments described herein provide in another aspect an apparatus for producing silicon from silica, comprising a vacuum electric arc furnace adapted to receive feedstock therein, a vacuum system for providing vacuum in the furnace, wherein a plasma arc created in the furnace is adapted to provide energy to reduce silica to silicon.

[0020] Moreover, the embodiments described herein provide in another aspect a process for reducing silica containing materials to silicon, comprising the steps of: [0021] providing a vacuum arc furnace; [0022] feeding silica containing materials into the furnace; and [0023] heating the silica containing materials in the furnace to produce a silicon metal.

Description

 

 

BRIEF DESCRIPTION OF THE DRAWINGS

[0024] For a better understanding of the embodiments described herein and to show more clearly how they may be carried into effect, reference will now be made, by way of example only, to the accompanying drawings, which show at least one exemplary embodiment, and in which:

[0025] FIG. 1 is a schematic vertical cross-sectional view of a vacuum arc silica to silicon reduction apparatus in accordance with an exemplary embodiment;

[0026] FIG. 2 is a schematic view of a silica to high purity silicon process in accordance with an exemplary embodiment; and

[0027] FIG. 3 is a graph of a vapor pressure of pure metal elements as a function of temperature in accordance with an exemplary embodiment.

DESCRIPTION OF VARIOUS EMBODIMENTS

[0028] In an embodiment, a vacuum electric arc furnace (VEAF) is used to produce high purity silicon (e.g., >99%) from silica containing materials in one-step. The arc is created in the vacuum furnace using either alternating current or direct current. The energy needed to reduce silica to silicon is provided by the plasma arc. The reducing agent for such reduction process is typically carbon due to its abundance and low price. Any carbon source with high reactivity with silica that possesses the impurities that mainly volatilize at vacuum condition can be processed. In case of silica containing materials such as quartz, the content of the impurities including, but not limited to, phosphorous (P), Zinc (Zn), Magnesium (Mg), Calcium (Ca), Lead (Pb), Manganese (Mn), Aluminum (Al), and Iron (Fe), can be lowered or totally removed. In the case of the higher vapor pressure species (relative to silicon), the removal rate is higher according to Hertz-Knudsen equation. For instance, P can be almost completely removed by the proposed process.

[0029] In the present embodiment, a mixture of silica containing material, for instance quartz, and a reducing agent, typically carbon, is transferred to the VEAF. The plasma arc created in the furnace delivers the necessary energy to reduce silica to silicon and volatilize impurities from the silicon phase under vacuum.

[0030] The vacuum electric arc silica reduction functions in a similar way to an electric arc furnace, but using vacuum conditions (<100 kPa, and more typically <1000 Pa) enables to volatilize impurities at lower temperatures and more effectively than they volatilize at atmospheric pressure. This makes it possible to volatilize these impurities at achievable moderate temperatures (1400-2000° C.) and high rate in the furnace with reduced contamination from the crucible. Moreover, those impurities, which are not volatile at ambient pressure such as Mn, Ag, Ga, Sn, Cu, Al, and Fe, become volatile at vacuum conditions. The intense heat from the plasma arc will provide an appropriate temperature for the reduction of silica to silicon in presence of the reducing agent such as carbon and provide enough heat to keep the silicon in molten phase during the refining process. The use of a vacuum electric arc process over an atmospheric electric arc process results in that impurities having higher vapor pressure than silicon will volatilize during the process. This allows for the production of higher purity silicon in one-step in contrast to the conventional method by which the MG-Si is refined through the post-purification processes.

[0031] Furthermore, the present embodiment results in that the quality of the silicon product is less dependent on the impurities in the raw materials, compared with known conventional methods. This becomes more important where the high purity silica or the high purity carbon source is unavailable or expensive.

[0032] Now turning to the drawings, FIG. 1 shows, in a schematic vertical cross-sectional view, a representation of the silica to silicon process in accordance with an exemplary embodiment, wherein reference A denotes generally an apparatus for producing silicon from silica. In the apparatus A, feedstock F is fed at 24 via one or multiple ports 1 to a vacuum electric arc furnace 2 (VEAF), with the feedstock F being piled up in a crucible 3 that is, for instance, made of low conductivity graphite. A moveable hollow graphite electrode(s) 4 carries current to an electrically conductive plate 5 that is, for instance, made of high conductivity graphite. The graphite electrode(s) 4 is hollow to allow at 25 for the introduction of arc stabilizing gases either inert, or reactive and to allow for the introduction of volatilizing chemical agents, those which produce volatile species by reacting with the impurities or enhance the volatilization rate of impurities from the melt.

[0033] An electric arc(s) 6 is formed directly between the electrode(s) 4 and the electrically conductive plate 5 at the beginning of the process, and thereby producing a silicon melt 7 thereafter. The melt 7 containing silicon is periodically tapped through a tap hole 8.

[0034] The operating pressure of the furnace 2 is regulated through a vacuum pump (not shown) connected to an outlet port 9. The furnace environment is controlled by introducing various gases, to carry over the volatilized impurities and gaseous by-products and to partially oxidize the monoxide gaseous species such as CO(g) and SiO(g) through a gas injection port 10.

[0035] The moving electrode(s) 4, which is displaced by a motion system to control the voltage(s) (not shown), is electrically insulated from the body of furnace 2 by electrically insulating material 11, such as machinable glass-ceramic, e.g. MACOR®. To decrease the heat loss of the furnace 2, the wall of the graphite crucible 3 is herein insulated by a low thermal conductive refractory material 12. To control the wall temperature of the furnace 2, a jacket 13 is herein attached to the exterior of the furnace 2, through which a cooling fluid either gas or liquid is introduced (not shown).

[0036] FIG. 2 shows a schematic representation of a complete silica to silicon production process in accordance with an exemplary embodiment, which includes a reduction section and a gas cleaning section. The reduction process of silica containing materials to high purity silicon (e.g., >99%) takes place in a furnace 14, such as the detailed furnace 2 described in FIG. 1. The hot gas evolving from the furnace spool mixed with the carrier gas vents off the furnace 14 to an oxygen-assisted refractory-lined cyclone 15. The role of the cyclone 15 is to collect the condensed impurities and silica from the gas phase and to oxidize combustible species, such as carbon monoxide. Air or oxygen is injected into the cyclone 15 through a manifold 16. Alternatively, a refractory-lined vessel fired by a fuel burner or an oxy-fuel burner (not shown) can be used to oxidize CO(g) to CO2(g) in the off-gas. The condensates and the carryover particulates are collected in a sealed collection pot 17.

[0037] The gas coming out of the cyclone 15 passes through a gas cooler-expander 18, where the gas is cooled down to reach temperatures below 80° C., and the particulates, from the condensates that are volatile in the cyclone 15, settle down and are collected in a collection box 19. The gas coming out of the gas cooler-expander 18 will pass through a high efficiency particulate air (HEPA) filtration system 20 to capture very fine particulates, e.g. <5 μm, escaping from the cyclone 15 and the gas cooler-expander 18. The gas, free of particulates, will pass through an activated carbon filter 21 to capture remaining noxious gaseous species such as Cl2, other chlorine containing gaseous species, SO2, and other acid gases from the off-gas. The operating pressure of the system is controlled by a vacuum pump 22. The off-gas is exhausted to a stack 23.

[0038] Returning to FIG. 1, the feedstock material F containing silica, which is either quartz or quartzite or any other forms with high silica content (>60-70%, the remaining to be mostly volatile impurities at the VEAF operating condition), and a reducing agent, which is typically carbon, is fed directly into the VEAF 2. The hollow electrode(s) 4, typically made of high quality graphite, conducts the current to the conductive plate 5 placed at the bottom of the furnace 2 through direct contact at the beginning of the process and thereafter, the plasma arc 6. The plasma arc 6 heats up the feedstock F to initiate the reduction reactions via SiO2(s,l)+C(s).

[0039] Gaseous by-product, in case of using carbon to be carbon monoxide (CO) via this overall reaction: SiO2(s)+2C(s)+Heat=Si (l)+2C0 (g), travels up and is vented out to an appropriate gas cleaning system as shown in FIG. 2. The gas cleaning system role is, for instance, to reduce the level of CO(g) below 50 ppm in the off-gas, to remove the noxious gaseous species, and to capture particulates from the gas coming out of the furnace 2. The silicon in liquid form is accumulated at the bottom of the crucible 3 and is periodically tapped out, at 8, from the furnace 2. Each tapping typically takes place between each reduction-refining process and depends on the removal rate of the impurities under vacuum condition. The heat from the arc 6 keeps the silicon and impurities in the molten phase. A very low operating pressure is provided for the volatilization of the impurities having higher vapor pressure than silicon.

[0040] The volatized impurities are vented out of the furnace 2 via an inert gas (such as Argon) or a reducing carrier gas (such as CO). To enhance the volatilization rate of the impurities, various volatilizing agents, such as chlorine containing material, can be injected through the hollow electrode(s) 4 into the melt 7. The volatilizing agents enhance the volatilization rate of impurities by reacting with them and producing new compound(s) with a greater volatility and/or by becoming volatile in the melt. For instance, by injecting chlorine (Cl2), impurities will be transformed to the metal salts, via M(l)+x/2 Cl2(g)=MClx(g), having much higher volatility than their metal form. The amount of volatilizing gas to be injected varies according to the amount of impurities and should be injected according to the stoichiometry of the reactions.

EXAMPLE

[0041] The difference in the vapor pressures of the metal components at elevated temperatures is the basic principle of the vacuum refining. The vapor pressures of selected pure substances between 1400° C. and 2000° C. were calculated using the available vapor pressure data of pure substances (shown in FIG. 3). It is seen that the vapor pressures of many elements which exist in the starting material (e.g. Quartz) are higher than that of silicon, and hence, they can be evaporated from the silicon phase. However, at atmospheric pressure (i.e., 1.013 E+05 Pa), only a few elements can be evaporated at temperatures around 2000° C., which is the temperature of the crater, i.e. the cavity which is created in the furnace burden by the formation of gaseous species from the raw materials, where the silicon metal accumulates.

[0042] On the other hand, by reducing the operating pressure of the process, e.g. to 100 Pa, all elements above the silicon line as shown in FIG. 3 will be evaporated at a temperature as low as 1900° C. Moreover, lowering the pressure will also help to perform the refining process at lower temperatures, which will lower the operating cost of the process. Additionally, vacuum refining enhances the mass transfer of volatile impurities from the liquid to the gas phase by reducing the resistance at the liquid-gas interface, which cannot be achieved at atmospheric pressure.

[0043] In one example, quartz raw material was reduced in the presence of carbon in the direct electric (DC) vacuum arc furnace operating at vacuum level of <0.5 kPa. The bottom of graphite crucible acted as the bottom anode to receive electrode from the cathode. The process was performed in the batch mode where quartz-carbon mixture (a mass ratio of 2.5 SiO2/C) was placed in the graphite crucible. Quartz sample had a purity of 98.99% and the carbon source metal impurity was assessed by ICP-MS to be 0.4%. The presence of silicon metal was detected in the produced sample collected from the bottom of crucible using scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM-EXD) method. The silicon phase purity was then quantified with a detection limit of 0.1% (1000 ppm). In one sample 22 readings showed the presence of 100% pure silicon metal with actual purity of greater than 99.9% with respect to the detection limit. In this example, 1% of impurity was present in the quartz sample while the carbon source contained 0.4% of metal impurities. The presence of silicon metal with purity greater than 99.9% indicates that not only silicon can be produced using this novel method but also this purity can be achieved in one step.

[0044] While the above description provides examples of the embodiments, it will be appreciated that some features and/or functions of the described embodiments are susceptible to modification without departing from the spirit and principles of operation of the described embodiments. Accordingly, what has been described above has been intended to be illustrative of the embodiments and non-limiting, and it will be understood by persons skilled in the art that other variants and modifications may be made without departing from the scope of the embodiments as defined in the claims appended hereto.

REFERENCES

[0045] [1] G. O. Seward and F. O. Kgelgen, “Production of Silicon”. U.S. Pat. No. 916,793, 30 Mar. 1909.

[0046] [2] A. M. Kuhlmann, “Silicon Metal Production”. U.S. Pat. No. 3,215,522, 2 Nov. 1965.

[0047] [3] Arvid N. Arvidson, Vishu D. Dosaj and James B. May, “Silicon Smelting Process in Direct Current Furnace”. U.S. Pat. No. 5,009,703, 23 Apr. 1991.

[0048] [4] Curtis W. Goins Jr. and Earl K. Stanley, “Smelting Apparatus for Making Elemental Silicon and Alloys Thereof”. U.S. Pat. No. 5,104,096, 14 April 1992.

Claims

 

 

1. An apparatus for producing silicon from silica, comprising a vacuum electric arc furnace adapted to receive feedstock therein, a vacuum system for providing vacuum in the furnace, wherein a plasma arc created in the furnace is adapted to provide energy to reduce silica to silicon.

2. The apparatus of claim 1, wherein a mixture of silica containing material, for instance quartz, and a reducing agent, for instance carbon, is adapted to be fed to the furnace.

3. The apparatus of any one of claims 1 and 2, wherein the furnace is adapted to operate under vacuum conditions, for instance <100 kPa, and more typically <1000 Pa.

4. The apparatus of any one of claims 1 to 3, wherein the plasma arc in the furnace is adapted to volatilize impurities from the silicon phase under vacuum and to provide heat for keeping the silicon in molten phase during a refining process.

5. The apparatus of claim 4, wherein the vacuum is adapted to volatize the impurities at low temperatures, such as at 1400-2000° C.

6. The apparatus of any one of claims 1 to 5, wherein the feedstock is fed to the furnace via at least one feedstock port, a crucible being provided for receiving the feedstock.

7. The apparatus of claim 6, wherein the feedstock is adapted to be piled up in the crucible.

8. The apparatus of any one of claims 6 to 7, wherein the crucible is made of low conductivity graphite.

9. The apparatus of any one of claims 1 to 8, wherein at least one electrode is provided for carrying current to an electrically conductive plate, for instance provided at a bottom of the crucible.

10. The apparatus of claim 9, wherein the conductive plate is made of high conductivity graphite.

11. The apparatus of any one of claims 9 to 10, wherein the electrode is hollow for allowing for the introduction of arc stabilizing gases in the furnace, either inert or reactive

12. The apparatus of claim 11, wherein the electrode is hollow for allowing for the introduction of volatilizing chemical agents, for reacting with impurities or enhance the volatilization rate of impurities from the melt.

13. The apparatus of any one of claims 9 to 12, wherein the electrode is made for instance of graphite.

14. The apparatus of any one of claims 9 to 13, wherein the electrode is moveable.

15. The apparatus of any one of claims 9 to 14, wherein the electric arc is adapted to be formed directly between the electrode and the conductive plate at the beginning of the process, thereby producing a silicon melt thereafter, the melt containing silicon.

16. The apparatus of claim 15, wherein an outlet is provided for periodically tapping the melt, in liquid form, from the furnace.

17. The apparatus of any one of claims 1 to 16, wherein the furnace environment is adapted to be controlled by introducing various gases in the furnace via a gas injection port, for carrying over the volatilized impurities and gaseous by-products and for partially oxidizing the monoxide gaseous species, such as CO(g) and SiO(g).

18. The apparatus of any one of claims 9 to 16, wherein the electrode is adapted to be displaced by a motion system to control the voltage(s).

19. The apparatus of any one of claims 9 to 16, wherein the electrode is adapted to be displaced by a motion system to control the voltage(s), the electrode being electrically insulated from « body of furnace by an electrically insulating material, such as machinable glass-ceramic, e.g. MACOR®.

20. The apparatus of any one of claims 1 to 19, wherein, to limit heat loss from the furnace, a wall of the crucible is insulated by a low thermal conductive refractory material.

21. The apparatus of any one of claims 1 to 20, wherein, to control a wall temperature of the furnace, a jacket is provided on an exterior of the furnace, through which a cooling fluid, either gas or liquid, is circulated.

22. The apparatus of any one of claims 9 to 16, 18 and 19, wherein the electrode is adapted to conduct current to the conductive plate placed at a bottom of the furnace through direct contact at the beginning of the process and thereafter, the plasma arc, with the plasma arc being adapted to heat up the feedstock to initiate the reduction reaction via SiO2(s,l)+C(s).

23. The apparatus of any one of claims 1 to 22, wherein the feedstock material contains silica, which is either quartz or quartzite or any other forms with high silica content, for instance >60-70%, the remaining being adapted to be mostly volatile impurities at the operating condition of the furnace, and with a reducing agent, typically carbon, being adapted to be fed directly into the furnace.

24. The apparatus of claim 16, wherein each tapping from the crucible is adapted to take place between each reduction-refining process and depends on a removal rate of the impurities under vacuum condition.

25. The apparatus of any one of claims 1 to 24, wherein a low operating pressure is adapted to be provided for the volatilization of impurities having higher vapor pressure than silicon.

26. The apparatus of any one of claims 1 to 25, wherein volatized impurities are adapted to be vented out of the furnace via an inert gas, such as Argon, or a reducing carrier gas, such as CO.

27. The apparatus of any one of claims 1 to 26, wherein to enhance the volatilization rate of the impurities, various volatilizing agents, such as chlorine containing material, are adapted to be injected through the hollow electrode into the melt.

28. The apparatus of any one of claims 1 to 27, wherein volatilizing agents are provided for enhancing a volatilization rate of impurities by reacting with the impurities producing new compound(s) with a greater volatility and/or by becoming volatile in the melt, for instance, by injecting chlorine (Cl2), impurities are adapted to be transformed to the metal salts, via M(l)+x/2 Cl2(g)=MClx(g), having much higher volatility than the metal form thereof.

29. A process for producing silicon from silica, using the apparatus of any one of claims 1 to 28.

30. The process of claim 29, comprising a reduction system and a gas cleaning system, a reduction process of silica containing materials to high purity silicon, e.g. >99%, taking place in the furnace.

31. The process of claim 30, wherein hot gas evolving from the furnace mixed with the carrier gas is adapted to be vented off the furnace to an oxygen-assisted refractory-lined cyclone.

32. The process of claim 31, wherein the cyclone is adapted to collect condensed impurities and silica from the gas phase and to oxidize combustible species, such as carbon monoxide.

33. The process of any one of claims 31 and 32, wherein air or oxygen is injected into the cyclone through a manifold.

34. The process of any one of claims 31 and 32, wherein a refractory-lined vessel fired by a fuel burner or an oxy-fuel burner is provided to oxidize CO(g) to CO2 (g) in the off-gas.

35. The process of any one of claims 31 to 34, wherein a sealed collection pot is provided for collecting condensates and carryover particulates.

36. The process of any one of claims 31 to 35, wherein gas coming from the cyclone is adapted to pass through a gas cooler-expander, where the gas is adapted to be cooled down to reach temperatures below 80° C., and the particulates, from the condensates that are volatile in the cyclone, are adapted to settle down and to be collected in a collection box.

37. The process of claim 36, wherein gas coming out of the gas cooler-expander is adapted to pass through a high efficiency particulate air (HEPA) filtration system for capturing very fine particulates, e.g. <5 μm, escaping from the cyclone and the gas cooler-expander.

38. The process of claim 37, wherein the gas, free of particulates, is adapted to pass through an activated carbon filter for capturing remaining noxious gaseous species, such as C12, other chlorine containing gaseous species, SO2, and other acid gases from the off-gas, and wherein an operating pressure is for instance controlled by a vacuum pump and the off-gas is exhausted to a stack.

39. The process of any one of claims 30 to 38, wherein gaseous by-product, in case of using carbon to be carbon monoxide (CO) via the following overall reaction: SiO2(s)+2C(s)+Heat=Si (l)+2C0 (g), is adapted to travel up and to be vented out to the gas cleaning system.

40. The process of claim 39, wherein the gas cleaning system is adapted, for instance, to reduce a level of CO(g) below 50 ppm in the off-gas, to remove the noxious gaseous species, and to capture particulates from the gas coming out of the furnace.

41. The apparatus of any one of claims 1 to 28, wherein the vacuum is provided by a vacuum pump in communication with the furnace, for instance via an outlet port.

42. The apparatus of any one of claims 1 to 28, wherein the operating pressure of the furnace is adapted to be regulated with a vacuum pump in communication with the furnace, for instance via an outlet port.

43. A system for reducing silica to silicon, which uses a combination of a plasma arc and vacuum, to produce high purity silicon from silica containing materials, such as quartz or quartzite.

44. The system of claim 43, wherein a vacuum electric arc furnace is provided, such that the plasma arc produces a silicon melt from the silica containing materials.

45. The system of claim 44, wherein, to enhance a volatilization rate of impurities contained in the silica containing materials, volatilizing agents, such as a chlorine containing material, are provided and are adapted to be injected through at least one hollow electrode into a melt produced in the furnace.

46. A vacuum electric arc furnace, comprising at least one set of hollow electrodes to generate an electric arc.

47. The vacuum electric arc furnace of claim 46, wherein there is provided at least one moving electrode, which is adapted to be displaced by a motion system to control the voltage(s) and which is electrically insulated from a body of furnace.

48. A process where the reduction process of silica containing materials to high purity silicon takes place in a vacuum arc furnace, the hot gas evolving from the furnace being oxidized in a refractory-lined cyclone used to condense and collect impurities, and to oxidize combustible species, such as carbon monoxide.

49. The process of claim 48, wherein the gas is further cleaned of condensable particulates in a gas cooler-expander and in a high efficiency particulate air (HEPA) filtration system to capture very fine particulates.

50. A process for reducing silica containing materials to silicon, comprising the steps of: providing a vacuum arc furnace; feeding silica containing materials into the furnace; and heating the silica containing materials in the furnace to produce a silicon metal.