HPQ Silicon Inc V.HPQ

Three-Dimensional Silicon Anodes

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Bucky sandwich electrodes containing Si NPs (diameter of ∼100 nm) exhibits up to ∼1200 and 1900% increases in the gravimetric capacity after 500 cycles at 0.1 C, respectively, when discharged to 0.1 V. Using detailed electrochemical impedance spectroscopy, we show that the diffusion time constants in the Bucky paper and Bucky sandwich electrodes are increased by 2 orders of magnitude compared to that in the bare Cu foil. Furthermore, we demonstrate that the Bucky paper and Bucky sandwich electrodes can withstand high rates up to 4 C and show long cycle life up to ∼500 cycles at 0.1 C. Finally, we show that the Bucky sandwich electrode architecture with smaller diameter Si NPs (∼30 nm) leads to capacities as high as ∼1490 mAh/g (∼1635 mAh/g) at 0.1 C up to 100 cycles when discharged to 0.1 V (0.01 V).


https://pubs.acs.org/doi/full/10.1021/acsami.0c05888


Not sure if this paper has been posted before, if so here it is again.. HPQ 2021 here we go!!