Scandium Canada Ltd V.SCD

Scandium applications: Sc as catalyst for green house gases

[ScandiumPower]

There are numerous applications where smalla amount of Scandium makes a miracle. In this catalyst application only a smalla amount of Sc (o.5%) in a microporous silica material was needed for almost complete reformation of methane (CH4)  and carbon dioxide (CO2) to hydrogen (H2) and carbon monoxide (CO).

''Abstract

This study investigated the performance of supported Ni catalysts in the utilization of greenhouse gases like CO2 and CH4 via dry reforming. The support SBA-15 was impregnated first with Sc at different loadings (0.5, 1, and 3 wt.%) and then with Ni (5 wt.%). The catalysts were first tested up to 8 h on stream with stoichiometric feed as well as methane in excess. The as-prepared catalysts were characterized using BET, XRD, TPR, CO2-TPD, XPS, TGA, and TEM.

This is in accordance with the surface area measurement, XRD, and TEM data. The Ni added to Sc-SBA-15 appeared to interact with both the support and Sc as the intensity and reduction temperature of the Sc promoted catalysts increased relatively to the unpromoted sample depending on Sc content.

The catalyst with 0.5 wt.% Sc loading led to the highest conversion and the lowest relative activity loss. The CH4 and CO2 conversions, on average, were 78 and 86 %, respectively, at the end of the runs at 750 °C. The final H2/CO ratio was 0.99, which is a good value compared to many literature catalysts. This catalyst also showed relatively constant CH4 and CO2 conversions over 80 h on stream. Increasing the Sc loading above 0.5 wt.% was not beneficial in terms of activity.''

https://www.sciencedirect.com/science/article/pii/S0016236122023560